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Ring closure of substituted 2 chlorosuccinates to or lactones has been studied by means of MP2/6 311+G(d,p)//MP2/6 31+G(d) calculations in water treated as a polarised continuum (PCM) and in vacuum. Optimised geometries have been obtained for 2 chlorosuccinate and its 2 methyl, 3,3 dimethyl, and 2,3,3 trimethyl derivatives, along with the transition structures and products for intramolecular nucleophilic displacement leading to the 3 or 4 membered rings. Relative enthalpies and Gibbs free energies of activation and reaction are presented, along…

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It’s not just the designers who’ve seen the value of cultivating the eyewear as fashion accessory notion. Cavicchioli said that over the last five years Luxottica has increased its advertising in fashion magazines and worked to get its brands noticed by influencers and trendsetters. “We’re using the category to make a statement as well,” she said.. Effective at 5 pm today, Public Health for Madison and Dane County has issued a countywide order to stop mass gatherings of 250 or…

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Dr. Stephen Bolick, founder CEO of Eye Care Associates, a locally owned and operated multi site optometric practice, has announced that the classic sunglass look of Ray Ban Wayfarer is now available in “Carolina Blue” a first of its kind. The sunglasses are available exclusively at any of Eye Care Associates 17 offices located throughout the Triangle, the Sandhills and in Wilmington.. Google announced it was working with von Furstenberg last fall. Earlier this month, the company confirmed that a…

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Photo credit: TOBY MELVILLE Getty ImagesIt said that upon hearing that Meghan and Harry wanted to live a more “ordinary” life, the Queen thought back to the two years between 1949 and 1951 where Prince Philip was serving as a naval officer and based in Malta. She often fly out to see him and it strengthened their relationship. This train of thought supposedly lead her to the idea that Meghan and Harry could enjoy a couple of years together in…

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It does however require some knowledge. Debian is available in 3 versions: stable, testing and unstable. Stable is perfect for servers, testing or unstable is best for desktop use. It’s boxy, rugged and has a whiff of Range Rover premium cool. In a three row crossover segment dominated by non descript family haulers, the Telluride stands out by subtly flying its family flag. It’s the cool dad in a leather jacket and Ray Ban Wayfarers standing next to the shlub…

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In a city, one Moby could self drive to a warehouse to replenish itself while another takes its place (the current model can be controlled remotely or driven by a human; the designers are still finalizing the autonomous technology, and it not yet legal for it to drive itself on Chinese roads). Stores could also help replenish each other, avoiding longer trips. Common in stores that one store has run out of milk, another has run out of eggs, but…

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Singhania graduated in commerce from the Bombay University and completed his Chartered Accountancy from the ICAI, Delhi with an all India rank. He has also earned the right to use the Chartered Financial Analyst designation, conferred by CFA Institute. Having travelled extensively across the world, Singhania has also attended many global investment conferences and seminars.. C’mon folks! Anyone who has ever spent any time outdoors should have known better than to light a fire OR leave a fire smoldering in…

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The Pentagon says the policy doesn’t block transgender individuals from service, but advocates say it is designed to operate as a comprehensive ban on their presence. Current military leaders have testified to Congress that transgender troops have not affected cohesion, while retired military leaders have decried the policy as misguided and damaging.”It’s a bigoted policy. It has not one shred of evidence behind it,” Ray Mabus, a former secretary of the Navy, told CNN. My love for agronomy sprouted from…

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Committees, commissions, and boards play a significant role in helping city staff, the Common Council and the Mayor in making decisions that affect the lives of Madison residents. The City of Madison values broad participation in these bodies and highly encourages people of color, persons with disabilities and members of other traditionally underrepresented groups to apply. Committee positions are open to City of Madison residents.. Many businesses now use this flexible and vibrant medium to advertise, promote and raise brand…

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One of the best solutions for this is choosing a dark bottom and then an attractive or printed color for the top. Nowadays it is not hard to mix and match bathing suits. You can also purchase a two piece swimsuit separately. The biggest and most recognisable names in online streaming will invariably offer free trials of their services. This means you can watch that series everyone is talking about for nothing. If you do choose to go down this…

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